Method for analyzing electrochemiluminescence transient process
2011
The invention relates to a method for analyzing the electrochemiluminescence transient process. By the method, the electrochemiluminescence system transient process can be effectively analyzed; current, electric potential, light intensity and time dynamic parameters can be acquired from the electrochemiluminescence system transient process to compared with stable state measurement; mathematical formula models are converted; and a kinetics mechanism of the reaction is explained from another aspect. The method comprises the following steps of: (1) starting to measure by using an electrochemiluminescence transient analyzer, cutting off a working electrode loop and a counter electrode loop when a system is positioned at any luminescence potential, and stopping applying voltage; and (2) allowing the system to enter the transient process, detecting the endurance time and the luminous intensity from any luminescence potential to luminescence annihilation in the transient process, calculating a corresponding light intensity-time curve or a region area, and comparing with the light intensity-time curve or the region area under a closed loop in the stable state process to obtain a reaction kinetics equation of the transient process.
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