Mechanism of 2,6-Dichloro-4,4′-bipyridine-Catalyzed Diboration of Pyrazines Involving a Bipyridine-Stabilized Boryl Radical

Toshimichi Ohmura,Yohei Morimasa,Tomoya Ichino,Yusuke Miyake,Yasujiro Murata,Michinori Suginome,Kunihiko Tajima,Tetsuya Taketsugu,Satoshi Maeda

Mechanism of 2,6-Dichloro-4,4′-bipyridine-Catalyzed Diboration of Pyrazines Involving a Bipyridine-Stabilized Boryl Radical

2021

Toshimichi Ohmura
Yohei Morimasa
Tomoya Ichino
Yusuke Miyake
Yasujiro Murata
Michinori Suginome
Kunihiko Tajima
Tetsuya Taketsugu
Satoshi Maeda

The mechanism of 4,4′-bipyridine-catalyzed diboration of pyrazines was studied by experimental observation of the intermediates and by theoretical calculations. Intermediary radical species were de...

Keywords:

mechanism
4,4'-Bipyridine
Catalysis
Medicinal chemistry
Bipyridine
Chemistry

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