Zirconium-Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming
2018
: C-saturated Pd0 nanoparticles with an extended phase boundary to ZrO2 evolve from a Pd0 Zr0 precatalyst under CH4 dry reforming conditions. This highly active catalyst state fosters bifunctional action: CO2 is efficiently activated at oxidic phase boundary sites and Pdx C provides fast supply of C-atoms toward the latter.
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