Practical Synthesis of a PCP-Type Pincer Ligand and Its Metal Complexes­

Kazutaka Matoba,Aya Eizawa,Shunsuke Nishimura,Kazuya Arashiba,Kazunari Nakajima,Yoshiaki Nishibayashi

Practical Synthesis of a PCP-Type Pincer Ligand and Its Metal Complexes

2017

Kazutaka Matoba
Aya Eizawa
Shunsuke Nishimura
Kazuya Arashiba
Kazunari Nakajima
Yoshiaki Nishibayashi

A synthetic method for N-heterocyclic carbene- and phosphine-based PCP-type pincer ligand is described on a large scale. Some transition-metal complexes bearing the PCP-type pincer ligand are prepared and characterized by X-ray crystal structure analysis.

Keywords:

Photochemistry
Chemistry
Carbene
Pincer ligand
Phosphine
Metal
Crystal structure
Polymer chemistry

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Practical Synthesis of a PCP-Type Pincer Ligand and Its Metal Complexes­

Practical Synthesis of a PCP-Type Pincer Ligand and Its Metal Complexes