NMR characterisation of unstable solvent and dihydride complexes generated at low temperature by in-situ UV irradiation

Cyril Godard,Philip Callaghan,Jenny L. Cunningham,Simon B. Duckett,Joost A. B. Lohman,Robin N. Perutz

NMR characterisation of unstable solvent and dihydride complexes generated at low temperature by in-situ UV irradiation

2002

Cyril Godard
Philip Callaghan
Jenny L. Cunningham
Simon B. Duckett
Joost A. B. Lohman
Robin N. Perutz

Low temperature in-situ UV irradiation of toluene solutions containing bis(alkene)rhodium complexes and parahydrogen in conjunction with NMR monitoring enables the characterisation of unstable η2-solvent complexes and dihydrogen activation products.

Keywords:

Toluene
Alkene
Organic chemistry
Irradiation
Spin isomers of hydrogen
Inorganic chemistry
Photochemistry
Solvent
Rhodium
Chemistry
In situ

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