Thermally-Induced Structural Transitions between Single-Crystalline States in the First Hybrid Compound Combining Keggin-Type Clusters with Metal-Cyclam Complexes: From 2-Dimensional Covalent Assemblies to Discrete Molecular Species

Leticia Fernández-Navarro,Amaia Iturrospe,Santiago Reinoso,Beñat Artetxe,Estibaliz Ruiz-Bilbao,Leire San Felices,Juan M. Gutiérrez-Zorrilla

Thermally-Induced Structural Transitions between Single-Crystalline States in the First Hybrid Compound Combining Keggin-Type Clusters with Metal-Cyclam Complexes: From 2-Dimensional Covalent Assemblies to Discrete Molecular Species

2020

Leticia Fernández-Navarro
Amaia Iturrospe
Santiago Reinoso
Beñat Artetxe
Estibaliz Ruiz-Bilbao
Leire San Felices
Juan M. Gutiérrez-Zorrilla

A hydrothermal reaction between the monolacunary polyoxometalate [SiW11O39]8–, a copper(II) salt, and 1,4,8,11-tetraazacyclotetradecane (cyclam) affords the first example of a hybrid compound combi...

Keywords:

Crystallography
Metal
hybrid compound
Cluster (physics)
Covalent bond
Chemistry
Cyclam
Crystal
Polyoxometalate
Copper

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