Patterning the direct write nano lithographic printing with solid features

The present invention includes a method of using a dip-pen nanolithography, including the step of depositing a solution having a block copolymer and an inorganic precursor on the substrate, to manufacture the organic / inorganic composite nanostructures onto a substrate. Nanostructures, including lines and / or dots of an array having a width / diameter of less than 1 micron. The present invention includes an apparatus comprising an inorganic / organic composite nano-scale region having nanoscale diameter than height.