Graphene in-situ load needle-shaped Co3O4 composite electrode material and manufacturing method thereof

The invention discloses a graphene in-situ load needle-shaped Co3O4 composite electrode material and a manufacturing method of the graphene in-situ load needle-shaped Co3O4 composite electrode material. Single-layer graphene with needle-shaped Co3O4 growing on the edge or two faces is adopted as a load frame of the composite electrode material, the plane size of a nanosheet layer is one micron to 50 microns, and the manufacturing method comprises the steps that graphite oxide is manufactured through a modified Hummers method, then ultrasonic treatment is carried out to obtain graphene oxide, a precursor of the composite electrode material is manufactured through the graphene oxide, and the precursor is annealed in inert atmosphere to obtain the composite electrode material. The manufacturing method of the composite electrode material is simple and environmentally friendly, according to the typical structure of the composite electrode material, the needle-shaped Co3O4 is combined with the surface or the side face of the graphene, a quasi two-dimensional nano structure is formed, the graphene sheet layer can be loaded with the needle-shaped Co3O4 in situ, the cycle life of the Co3O4 is prolonged, and the specific capacitance and other good electrochemical performance are improved.