Steric Modification of Metal-Phosphorus Bond Lengths: the Preparation, Characterization and CrystalStructures of mer-trans -(PPr i 3 ) 2 (Pme 2 Ph)-Cl- cis -H 2 Ir III (1) and mer-trans -(PPr i 3 ) 2 (PMe 2 Ph)H 3 Ir III