Gas transfer velocities of methane and carbon dioxide in a subtropical shallow pond

Two diel field campaigns under different weather patterns were carried out in the summer and autumn of 2013 tomeasureCO2 andCH4 fluxes and toprobe the rates of gas exchange across the air water interface in a subtropical eutrophic pond in China. Bubble emissions of CH4 accounted for 99.7 and 91.67% of the total CH4 emission measured at two sites in the summer; however, nobubblewas observed in the autumn.The pondwas supersaturated withCO2 andCH4 during themonitoring period, and the saturation ratios (i.e. observed concentration/equilibrium concentration) of CH4 were much higher than that of CO2. Although the concentration of dissolved CO2 in the surface water collected in the autumn was 1.24 times of that in the summer, the mean diffusive CO2 flux across the water air interface measured in the summer is almost twice compared with that in the autumn. The mean concentration of dissolved CH4 in the surface water in the autumn was around half of that in the summer, but the mean diffusive CH4 flux in the summer is 4 5 times of that in the autumn.Our data showed that the variation in gas exchange rate was dominated by differences in weather patterns and primary production. Averaged k600-CO2 and k600-CH4 (the gas transfer velocity normalised to a Schmidt number of 600) were 0.65 and 0.55 cm/h in the autumn, and 2.83 and 1.64 cm/h in the summer, respectively. No statistically significant correlation was found between k600 andU10 (wind speed at 10mheight) in the summer at lowwind speeds in clearweather.Diffusive gas fluxes increased during the nights, which resulted from the nighttime cooling effect of water surface and stronger turbulent mixing in the water column. The chemical enhancements for CO2 were estimated up to 1.94-fold in the hot and clear summer with low wind speeds, which might have been resulted from the increasing hydration reactions in water due to the high water temperature and active metabolism in planktonic algae. However, both the air and surface water temperatures decreased continually, and relatively lower temperature and overcast weather with occasionally light rain dominated the second campaign in the autumn. The concentration of dissolved oxygen in the surfacewater and U10 controlled gas transfer velocities of CO2 and CH4, respectively, in the cool autumn. When the surface water temperaturewashigher than the air temperature, higherCO2 fluxwasobservedbecause thewaterbodywasunstable and overturned quickly, inducing quick CO2 emitted from plankton algae in surface water to the atmosphere.