Enantioselective Addition of Heteroarylboronates to Arylimines Catalyzed by a Rhodium‐Diene Complex.

Rhodium-diene complex RDPT is an efficient catalyst for the enantioselective 1,2-addition of heteroarylboronates (II) to aryl N-tosylimines (I) and aryl N-nosylimine (VII).