Reaktionen von Dithiocarbonsäureestern mit CH-acidem Isothiocyanatoessigester - Eine neue Synthese von 2-Methylthio-1,3-thiazolen
1990
Methyl arylcarbodithioates react with ethyl isothiocyanatoacetate in the presence of sodium hydride in tetrahydrofuran to give the sodium salts of ethyl 5-aryl-2-mercapto-1,3-thiazole-4-carboxylates. In situ methylation affords the corresponding 2-methylthio derivatives
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