Arigid pentacoordinate silicon structure generalization of pseudorotation
1986
Abstract Examination of an organosilicon compound with a structure very favorable for pentacoordination shows the generality of the pseudorotation at silicon for bi- and tri-functional compounds. In contrast monofunctional compounds do not undergo pseudorotation, the Δ G * being estimated to be > 20 kcal M −1 .
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