A Highly Regio- and Stereoselective C5 Oxyfunctionalization of Coprostane Steroids by Dioxiranes: An Improved Access to Progestogen and Androgen Hormones.
1993
Abstract Coprostane steroids are selectively oxyfunctionalized at C 5 by dimethyldioxirane and methyltrifluoromethyldioxirane to give useful intermediates for bioactive compounds.
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