Syntheses of photoactive complexes. Electronic spectra, electrochemistry, and SCF-X.alpha.-DV calculations for bis(phosphine)palladium oxalate and dithiooxalate complexes. Crystal and molecular structures of (dithiooxalato-S,S')bis(trimethylphosphine)palladium(II) and (1,1-dithiooxalato-S,S')bis(.mu.3-sulfido)-2,2,3,3-tetrakis(trimethylphosphine)-triangulo-tripalladium(II)

Robert L. Cowan,Daniel B. Pourreau,Arnold L. Rheingold,Steven J. Geib,William C. Trogler

Syntheses of photoactive complexes. Electronic spectra, electrochemistry, and SCF-X.alpha.-DV calculations for bis(phosphine)palladium oxalate and dithiooxalate complexes. Crystal and molecular structures of (dithiooxalato-S,S')bis(trimethylphosphine)palladium(II) and (1,1-dithiooxalato-S,S')bis(.mu.3-sulfido)-2,2,3,3-tetrakis(trimethylphosphine)-triangulo-tripalladium(II)

1987

Robert L. Cowan
Daniel B. Pourreau
Arnold L. Rheingold
Steven J. Geib
William C. Trogler

[Pd(S 2 C 2 O 2 )(PMe 3 ) 2 ] cristallise dans le systeme orthorhombique, groupe d'espace Pbca et sa structure est affinee jusqu'a R=0,0263. [Pd 3 (S 2 C 2 O 2 )(μ-S) 2 (PMe 3 ) 4 ] cristallise dans le systeme monoclinique, groupe d'espace P2 1 avec R=0,0250

Keywords:

Oxalate
Electrochemistry
Trimethylphosphine
Photochemistry
Palladium
Phosphine
Inorganic chemistry
Carboxylate
Chemistry
X-ray crystallography
Inorganic compound
Stereochemistry
Medicinal chemistry
Crystal structure

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