{6,6′-Dimethyl-2,2′-bis­[(2-oxido­benzyl­idene)amino]-1,1′-biphenyl-κ4O,N,N′,O′}bis­(propan-2-olato-κO)titanium(IV) n-hexane hemisolvate

Liang Chen,Xuebin Deng

{6,6′-Dimethyl-2,2′-bis[(2-oxidobenzylidene)amino]-1,1′-biphenyl-κ4O,N,N′,O′}bis(propan-2-olato-κO)titanium(IV) n-hexane hemisolvate

2016

Liang Chen
Xuebin Deng

The mononuclear TiIV title complex, [Ti(C28H22N2O2)(C3H7O)2]·0.5C6H14, crystallizes as an n-hexane hemisolvate. The TiIV atom is coordinated by a dianionic tetradentate biphenyl Schiff base ligand and two O atoms of two propan-2-olate anions in a distorted TiN2O4 octahedral coordination geometry, in which the two N atoms are in a cis configuration. In the crystal, complex molecules are stacked parallel to [100], leaving space for channels parallel to [001] where the solvent molecules are located.

Keywords:

Schiff base
Chemistry
Cis–trans isomerism
Photochemistry
Stereochemistry
Titanium
Crystal structure
Coordination geometry
Biphenyl
Solvent
Ligand
Inorganic chemistry
Hexane

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{6,6′-Dimethyl-2,2′-bis­[(2-oxido­benzyl­idene)amino]-1,1′-biphenyl-κ4O,N,N′,O′}bis­(propan-2-olato-κO)titanium(IV) n-hexane hemisolvate

{6,6′-Dimethyl-2,2′-bis[(2-oxidobenzylidene)amino]-1,1′-biphenyl-κ4O,N,N′,O′}bis(propan-2-olato-κO)titanium(IV) n-hexane hemisolvate