A regio- and stereoselective synthesis of trisubstituted alkenesviagold(I)-catalyzed hydrophosphoryloxylation of haloalkynes
2011
A new stereoselective synthesis of trisubstituted alkenes is developed. Hydrophosphoryloxylation of haloalkynes provides Z-alkenyl halophosphates, which undergo Pd-catalyzed consecutive cross-coupling reactions to afford regio- and stereodefined trisubstituted alkenes.
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