Stereochemistry of reductive dehalogenation with deuterium gas

Frans M. Kaspersen,Eric M. G. Sperling

Stereochemistry of reductive dehalogenation with deuterium gas

1986

Frans M. Kaspersen
Eric M. G. Sperling

The stereochemistry of reductive debromination and deiodination of 4-haloprolines and 2- or 7-bromo-cholesterols with 2H2 catalyzed by Pd was investigated using 2H NMR. The reactions are stereoselective but not stereospecific.

Keywords:

Chemistry
Stereospecificity
Biochemistry
Organic chemistry
Halogenation
Stereochemistry
Deuterium
Catalysis
Stereoselectivity

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