Concentration and Recovery of Dyes from Textile Wastewater Using a Self-Standing, Support-Free Forward Osmosis Membrane

Forward osmosis (FO) can potentially treat textile wastewaters with less fouling than pressure-driven membrane processes such as reverse osmosis and nanofiltration. However, conventional FO membranes with asymmetric architecture experience severe flux decline caused by internal concentration polarization and fouling as dye molecules accumulate on the membrane surface. In this study, we present a new strategy for concentrating dye by using a self-standing, support-free FO membrane with a symmetric structure. The membrane was fabricated by a facile solution-casting approach based on a poly(triazole-co-oxadiazole-co-hydrazine) (PTAODH) skeleton. Due to its dense architecture, ultrasmooth surface, and high negative surface charge, the PTAODH membrane exhibits excellent FO performance with minimal fouling, low reverse salt flux, and negligible dye passage to the draw solution side. Cleaning with a 40% alcohol solution, after achieving a concentration factor of ∼10, resulted in high flux recovery ratio (98.7%) ...