Ancillary ligand effect on single-site styrene polymerization: isospecificity of group 4 metal bis(phenolate) catalysts.

Carmine Capacchione,Antonio Proto,Henner Ebeling,Rolf Mülhaupt,Klaus B. Møller,Thomas P. Spaniol,Jun Okuda

Ancillary ligand effect on single-site styrene polymerization: isospecificity of group 4 metal bis(phenolate) catalysts.

2003

Carmine Capacchione
Antonio Proto
Henner Ebeling
Rolf Mülhaupt
Klaus B. Møller
Thomas P. Spaniol
Jun Okuda

Styrene is polymerized isospecifically by group 4 metal complexes that contain a C2-symmetrically coordinated 1,4-dithiabutane-linked bis(phenolato) ligand activated by methylaluminoxane.

Keywords:

Styrene
Inorganic chemistry
Organic chemistry
Catalysis
Polymerization
Methylaluminoxane
Metal
Ligand
Chemistry
catalyst selectivity
single site
Polymer chemistry

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