Hydrosilylation of unsaturated amines with oligodimethylsiloxanes containing terminal Si-bonds and physicochemical properties of the compounds obtained

This article studies the catalytic influence of 12 sets of platinum group metals (Pt(Ph 3 P) 4 ; Ir(CO)(PPh 3 ) 3 ; RhCl 2 (PPh 3 ) 3 ; Pdacac(PPh 3 ); Rh(C 8 H 14 ) 2 Cl; [Rh(CO) 2 Cl] 2 ; Rh(CO)(PPh 3 )H; [Rh(CO)C 8 H 14 )Cl] 2 ; Rhacac(CO) 2 ; Rh(CO) 2 acac(C 8 H 14 ); Rh(PPh 3 ) 2 Cl; Rhacac(CO)(PBu 3 )) on the reaction of 1,1,2,3-tetramethyldisiloxane with allylamine. The reaction was conducted at 140°C with a proportion of the reactants of 1:2:1