Experimental and Computational Study of Isomerically Pure Soluble Aza-phthalocyanines and Azasubphthalocyanines of Varying Number of Aza Units

Herein, we present a series of isomerically pure, peripherically alkyl substituted, soluble and low aggregating azaphthalocyanines as well as their new, smaller hybrid homologues, the azasubphthalocyanines. The focus lies on the effect of the systematically increasing number of aza building blocks [-N=] replacing the non peripheral [-CH=] units and its influence on physical and photophysical properties of these chromophores. The absolute and relative HOMO-LUMO energies of azaphthalocyanines was analyzed using UV-Vis, CV and compared to density functional theory calculations (B3LYP, TD-DFT). Crystals of substituted subphthalocyanine, N2-Pc*H2 and N4-[Pc*Zn$\cdot$H2O] were obtained out of DCM. For the synthesis of the valuable tetramethyltetraline phthalocyanine building block a new highly efficient synthesis involving a nearly quantitative CoII catalyzed aerobic autoxidation step is introduced replacing inefficient KMnO4/pyridine as oxidant. The lowering of the HOMO level is revealed as the determining factor for the trend in the adsorption energies by electronic structure analysis.