Synthesis of 2,2′‐bipyridyl‐type compounds via the suzuki‐miyaura cross‐coupling reaction
2007
2,2′-Bipyridyl-type compounds may be prepared by Suzuki-Miyaura coupling of a 2-pyridylboronic ester with 2-haloazines and -azoles. Ten examples are presented with yields of 47 to 84%. Both arylbromides and arylchlorides undergo the coupling, but the reaction is sensitive to ring substitution adjacent to the halogen.
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