Meteoric Metal Chemistry in the Martian Atmosphere

Recent measurements by the Imaging Ultraviolet Spectrograph (IUVS) instrument on NASA's Mars Atmosphere and Volatile EvolutioN (MAVEN) mission show that a persistent layer of Mg + ions occurs around 90 km in the Martian atmosphere, but that neutral Mg atoms are not detectable. These observations can be satisfactorily modeled with a global ablation rate of 0.06 metric tonnes of magnesium sol -1 , out of a cosmic dust input of 2.7 ± 1.6 t sol -1 . The absence of detectable Mg at 90 km requires that at least 50% of the ablating Mg atoms ionize through hyperthermal collisions with CO 2 molecules. Dissociative recombination of MgO + .(CO 2 )n cluster ions with electrons to produce MgCO 3 directly, rather than MgO, also avoids a buildup of Mg to detectable levels. The meteoric injection rate of Mg, Fe and other metals – constrained by the IUVS measurements - enables the production rate of metal carbonate molecules (principally MgCO 3 and FeCO 3 ) to be determined. These molecules have very large electric dipole moments (11.6 and 9.2 Debye, respectively), and thus form clusters with up to 6 H 2 O molecules at temperatures below 150 K. These clusters should then coagulate efficiently, building up metal carbonate-rich ice particles which can act as nucleating particles for the formation of CO 2 -ice clouds. Observable mesospheric clouds are predicted to occur between 65 and 80 km at temperatures below 95 K, and above 85 km at temperatures about 5 K colder.