On single-phase status and segregation of an as-solidified septenary refractory high entropy alloy

Phase predictions and characterizations on as-solidified septenary refractory high-entropy alloy, CrMoNbReTaVW, are presented. The simulated solidification process predicts a single body-centered-cubic (BCC) crystal structure with the tendency of compositional segregation. X-ray diffraction results confirm the “single-phase-like” BCC structure, while further experimental characterizations reveal the existence of multiple grains with significantly different compositions yet the same crystal structure and similar lattice parameters.