Poly[[(μ4-benzene-1,3,5-tri­carboxyl­ato-κ4O1:O1′:O2:O3)bis­(2,2-bi­pyridine-κ2N,N′)(μ2-hydroxido)dicopper(II)] trihydrate]

2014 
In the title two-dimensional coordination polymer, {[Cu2(C9H3O6)(OH)(C10H8N2)2]·3H2O}n, each of the two independent CuII atoms is coordinated by a bridging OH group, two O atoms from two benzene-1,3,5-tri­carboxyl­ate (L) ligands and two N atoms from a 2,2- bi­pyridine (bipy) ligand in a distorted square-pyramidal geometry. Each L ligand coordinates four CuII atoms, thus forming a polymeric layer parallel to the bc plane with bipy molecules protruding up and down. The lattice water mol­ecules involved in O—H⋯· O hydrogen bonding are situated in the inner part of each layer. The crystal packing is consolidated by π–π inter­actions between the aromatic rings of bipy ligands from neigbouring layers [inter­centroid distance = 3.762 (3) A].
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