An Enantiomerically Pure Pyridine NC-Palladacycle Derived from [2.2]Paracyclophane
2014
An enantiomerically pure planar chiral pyridine-based palladacycle was prepared from [2.2]paracyclophane in just four steps. The palladacycle shows potential in catalysis, mediating the Suzuki coupling of an aryl chloride. It also permits the ortho bromination of [2.2]paracyclophane, a reaction that can be hard to achieve selectively.
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