Total synthesis of new 1,5-bissubstituted myo-inositol derivatives. Synthesis of D-myo-inositol 1,5-bisphosphate, 3,5-bisphosphate and of rac. 1,5-Bissulphated and 1,5-bissulphamoylated isosteric analogues

Pieter Westerduin,Henrica A.M. Willems,Constant A. A. van Boeckel

Total synthesis of new 1,5-bissubstituted myo-inositol derivatives. Synthesis of D-myo-inositol 1,5-bisphosphate, 3,5-bisphosphate and of rac. 1,5-Bissulphated and 1,5-bissulphamoylated isosteric analogues

1990

Pieter Westerduin
Henrica A.M. Willems
Constant A. A. van Boeckel

Abstract Convenient synthesis of D-myo-inositol 1,5-bisphosphate, 3,5-bisphosphate and isosteric rac. 1,5-bissulphate and 1,5-bissulphonamide was accomplished from key intermediate 2,3,4,6-tetra-O-benzyl-myo-inositol.

Keywords:

Total synthesis
Cyclitol
Organic chemistry
Inositol
Enantiomer
Chemistry
Biochemistry
Stereochemistry

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