Alkaloids from leaves and stems of Vallesia glabra

: Eleven known indole alkaloids: vallesine, aspidospermine, 11-methoxydichotine, apparicine, tubotaiwine, vincadifformine, condylocarpine, (-)-rhazinilam, aspidospermatine, haplocidine, and 18-oxohaplocidine, have been isolated from leaves and stems of Vallesia glabra (Cav.) Link. (Apocynaceae) from Bolivia. Analysis of 2 D NMR spectra complete previous 1H and 13C data for vallesine, aspidospermine, and 11-methoxydichotine.