Synthesis, crystal structure and Hirshfeld surface analysis of diethyl 2,6-dimethyl-4-(thio­phen-3-yl)-1,4-di­hydro­pyridine-3,5-di­carboxyl­ate

2019 
In the title compound, C17H21NO4S, the 1,4-di­hydro­pyridine ring has an envelope conformation with the Csp3 atom at the flap. The thio­phene ring is nearly perpendicular to the best plane through the 1,4-di­hydro­pyridine ring, the dihedral angle being 82.19 (13)°. In the crystal, chains running along the b-axis direction are formed through N—H⋯O inter­actions between the 1,4-di­hydro­pyridine N atom and one of the O atoms of the ester groups. Neighbouring chains are linked by C—H⋯O and C—H⋯π inter­actions. A Hirshfeld surface analysis shows that the most prominent contributuion to the surface contacts are H⋯H contacts (55.1%).
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