[Preparation, characterization and adsorption performance of mesoporous activated carbon with acidic groups].

Mesoporous activated carbons containing acidic groups were prepared with cotton stalk based fiber as raw materials and H3PO4 as activating agent by one step carbonization method.Effects of impregnation ratio,carbonization temperature and heat preservation time on the yield,elemental composition,oxygen-containing acid functional groups and adsorptive capacity of activated carbon were studied.The adsorption capacity of the prepared activated carbon AC-01 for p-nitroaniline and Pb(Ⅱ) was studied,and the adsorption mechanism was also suggested according to the equilibrium experimental results.The maximum yield of activated carbons prepared from cotton stalk fiber reached 35.5% when the maximum mesoporous volume and BET surface area were 1.39 cm3.g-1 and 1 731 m2.g-1,respectively.The activated carbon AC-01 prepared under a H3PO4/ precursor ratio of 3∶ 2 and activated at 900℃ for 90 min had a total pore volume of 1.02 cm3.g-1,a micoporous ratio of 31%,and a mesoporous ratio of 65%.The pore diameter of the mesoporous activated carbon was mainly distributed in the range of 2-5 nm.The Langmuir maximum adsorption capacities of Pb(Ⅱ) and p-nitroaniline on cotton stalk fiber activated carbon were 123 mg·g-1 and 427 mg·g-1,respectively,which were both higher than those for commercial activated carbon fiber ACF-CK.The equilibrium adsorption experimental data showed that mesopore and oxygencontaining acid functional groups played an important role in the adsorption.