Free tropospheric aerosols at the Mt. Bachelor Observatory: more oxidized and higher sulfate content compared to boundary layer aerosols
2018
Abstract. Understanding the properties and life cycle processes of aerosol particles in
regional air masses is crucial for constraining the climate impacts of
aerosols on a global scale. In this study, characteristics of aerosols in the
boundary layer (BL) and free troposphere (FT) of a remote continental region
in the western US were studied using a high-resolution time-of-flight aerosol
mass spectrometer (HR-AMS) deployed at the Mount Bachelor Observatory (MBO;
2763 m a.s.l.) in central Oregon in summer 2013. In the absence of wildfire
influence, the average ( ± 1 σ ) concentration of non-refractory
submicrometer particulate matter (NR- PM 1 ) at MBO was 2.8 ( ± 2.8)
µ g m −3 and 84 % of the mass was organic. The other
NR- PM 1 components were sulfate (11 %), ammonium (2.8 %),
and nitrate (0.9 %). The organic aerosol (OA) at MBO from these clean
periods showed clear diurnal variations driven by the boundary layer dynamics
with significantly higher concentrations occurring during daytime, upslope
conditions. NR- PM 1 contained a higher mass fraction of sulfate and
was frequently acidic when MBO resided in the FT. In addition, OA in the FT
was found to be highly oxidized (average O∕C of 1.17) with low
volatility while OA in BL-influenced air masses was moderately oxidized
(average O∕C of 0.67) and semivolatile. There are indications that
the BL-influenced OA observed at MBO was more enriched in organonitrates and
organosulfur compounds (e.g., MSA) and appeared to be representative of
biogenic secondary organic aerosol (SOA) originated in the BL. A summary of
the chemical compositions of NR- PM 1 measured at a number of other
high-altitude locations in the world is presented and similar contrasts
between FT and BL aerosols were observed. The significant compositional and
physical differences observed between FT and BL aerosols may have important
implications for understanding the climate effects of regional background
aerosols.
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