Copper-Catalyzed Silylation of Cyclopropenes Using (Trifluoromethyl)trimethylsilane.
2008
A variety of cyclopropenes undergo direct silylation using (trifluoromethyl)trimethylsilane in the presence of a copper–bisphosphine catalyst; under these conditions, cyclopropenes that might otherwise undergo ring-opening are silylated efficiently.
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