Reaction of Arynes with Vinylogous Amides: Nucleophilic Addition to the ortho-Quinodimethide Intermediate.

Ran Li,Xuemei Wang,Zhibin Wei,Chunrui Wu,Feng Shi

Reaction of Arynes with Vinylogous Amides: Nucleophilic Addition to the ortho-Quinodimethide Intermediate.

2014

Ran Li
Xuemei Wang
Zhibin Wei
Chunrui Wu
Feng Shi

Vinylogous amides react with arynes in a [2 + 2] cycloaddition/ring-opening sequence to furnish an electronically instable ortho-quinodimethide intermediate.

Keywords:

Aryne
Cycloaddition
Nucleophilic addition
Organic chemistry
Chemistry

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