Synthesis of Polyazapolycyclic Caged Polynitramines.

Abstract Syntheses of new polyazapolycyclic caged polynitramines are described. Sequentially reacting 4,10-dibenzyl-2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazaisowurtzitane (5a) with NOBF4 and NO2BF4 in sulfolane solvent produces 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9.03,11]dodecane, 6). Syntheses of two new polyazapolycyclic caged trinitramines, 3,5,12-trinitro-3,5,12-triazawurtzitane (7a) and 2,4,10-trinitro-2,4,10-triazaadamantane (12a), as well as their labile parent secondary amines, are discussed. A new caged polynitrosamine, 3,5,12-trinitroso-3,5,12-triazawurtzitane (7d), has been obtained by ring-cleavage nitrosation of the new hexamine-wurtzitane compound 3,5,7,9-tetraazahexacyclo-[9.3.1.13,7.02,9.04,13.05,10]-hexadecane (10).