Effect of the Lead(II) Bond Angle on the Reactivity of Diaminoplumbylenes toward Ammonia: From Inertness to Immediate Ammonolysis

The reactivity of the N-heterocyclic plumbylenes o-C6H4(NSiRMe2)2Pb (R = Me, t-Bu), nap(NSiRMe2)2Pb (nap = naphthalene-1,8-diyl; R = Me, t-Bu), and [Fe{(η5-C5H4)NSit-BuMe2}2Pb] as well as of the ac...