Space-Charge-Mediated Anomalous Ferroelectric Switching in P(VDF–TrEE) Polymer Films

We report on the switching dynamics of P(VDF–TrEE) copolymer devices and the realization of additional substable ferroelectric states via modulation of the coupling between polarizations and space charges. The space-charge-limited current is revealed to be the dominant leakage mechanism in such organic ferroelectric devices, and electrostatic interactions due to space charges lead to the emergence of anomalous ferroelectric loops. The reliable control of ferroelectric switching in P(VDF–TrEE) copolymers opens doors toward engineering advanced organic memories with tailored switching characteristics.