Unexpected Nickel Complex Speciation Unlocks Alternative Pathways for the Reactions of Alkyl Halides with dppf-Nickel(0)

Megan Greaves,Thomas Oliver Ronson,Guy C. Lloyd Jones,Feliu Maseras,Stephen Sproules,David J. Nelson

Unexpected Nickel Complex Speciation Unlocks Alternative Pathways for the Reactions of Alkyl Halides with dppf-Nickel(0)

2020

Megan Greaves
Thomas Oliver Ronson
Guy C. Lloyd Jones
Feliu Maseras
Stephen Sproules
David J. Nelson

The mechanism of the reactions between dppf-Ni0 complexes and alkyl halides has been investigated using kinetic and mechanistic experiments and DFT calculations. The active species is [Ni(κ2-dppf)(...

Keywords:

Reaction mechanism
Chemistry
Catalysis
Alkyl
Nickel
Halide
Organometallic chemistry
Computational chemistry
Speciation

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