Characterization of an Am-Be PGNAA set-up developed for in situ liquid analysis: Application to domestic waste water and industrial liquid effluents analysis

A prompt gamma neutron activation analysis (PGNAA) set-up with an Am–Be source developed for in situ analysis of liquid samples is described. The linearity of its response was tested for chlorine and cadmium dissolved in water. Prompt gamma efficiency of the system has been determined experimentally using prompt gamma of chlorine dissolved in water and detection limits for different elements have been derived for domestic waste water. A methodology to analyze any kind of liquid is then proposed. This methodology consists mainly on using standards with water as bulk or in the case of absolute method, to use gamma efficiency determined with prompt gammas emitted by chlorine dissolved in water. To take into account the thermal neutron flux variations inside the samples, flux monitoring was carried out using a He-3 neutron detector placed at the external sample container surface. Finally, to correct for the differences in gamma attenuation, average gamma attenuations factors were calculated using MCNP5 code. This method was then checked successfully by determining cadmium in industrial phosphoric acid and our result was in good agreement with that obtained with inductively coupled plasma (ICP) method.