Complex formation of carbonyls, carboxylates, and acetylacetonates of main-group and transition metals with hydroperoxides and alcohols

The thermodynamic and structural parameters of complexes formed by secondary and tertiary alcohols and hydroperoxides with carbonyls, carboxylates, and acetylacetonates of variable-valence metals were determined. The complexes of s and 3d elements with hydroperoxides have different structures.