AIBN-Initiated Oxidative C-H Functionalization of Simple Alcohols with Diaryl(arylethynyl)phosphine Oxides: A Metal-free Approach towards Hydroxymethyl Benzo[b]phosphole Oxides and 6H-indeno[2,1-b]phosphindole 5-oxide Derivatives.

Jiami Guo,Chenlu Mao,Bin Deng,Liyi Ye,Yingwu Yin,Yuxing Gao,Song Tu

AIBN-Initiated Oxidative C-H Functionalization of Simple Alcohols with Diaryl(arylethynyl)phosphine Oxides: A Metal-free Approach towards Hydroxymethyl Benzo[b]phosphole Oxides and 6H-indeno[2,1-b]phosphindole 5-oxide Derivatives.

2020

Jiami Guo
Chenlu Mao
Bin Deng
Liyi Ye
Yingwu Yin
Yuxing Gao
Song Tu

The first metal-free and facile radical addition/cyclization of simple alcohols with diaryl(arylethynyl)phosphine oxides has been described with AIBN as radical initiator, affording an efficient an...

Keywords:

Oxide
Phosphole
Metal
Hydroxymethyl
Radical initiator
Organic chemistry
Surface modification
Phosphine
Chemistry
Polymer chemistry
Oxidative phosphorylation
Azobisisobutyronitrile

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