Visible Light Driven Organic Pollutants Degradation with Hydrothermally Carbonized Sewage Sludge and Oxalate Via Molecular Oxygen Activation

Converting sewage sludge into functional environmental materials has become an attractive sewage sludge disposal route. In this study, we synthesize a sewage sludge-based material via a facile one-pot hydrothermal carbonization method and construct a visible light molecular oxygen activation system with hydrothermally carbonized sewage sludge (HTC-S) and oxalate to degrade various organic pollutants. It was found that iron species of HTC-S could chelate with oxalate to generate H2O2 via molecular oxygen activation under visible light, and also promote the H2O2 decomposition to produce •OH for the fast organic pollutants degradation. Taking sulfadimidine as the example, the apparent degradation rate of HTC-S/oxalate system was almost 5–20 times that of iron oxides/oxalate system. This outstanding degradation performance was attributed to the presence of iron-containing clay minerals in HTC-S, as confirmed by X-ray diffraction measurements and Mossbauer spectrometry. In the oxalate solution, these iron-cont...