Root causes of intergranular attack in an operating nuclear steam generator tube

This paper reports the secondary side intergranular attack of an Alloy 600 tube, which was located within sludge piles in the hot-leg side of an operating nuclear steam generator. Carbide distribution along the grain boundaries and chromium depletion were analyzed using optical microscopy and transmission electron microscopy. Local crevice chemistry in contact with the defect was also assessed from the hideout return test data and oxide film analysis results using energy dispersive spectroscopy. The main causes of this defect are discussed based on the microstructure, local chemistry and operation temperature.