Crystal structure of N,N-diisopropyl-4-methyl­benzene­sulfonamide

2020 
The synthesis of the title compound, C13H21NO2S, is reported here along with its crystal structure. This compound crystallizes with two mol­ecules in the asymmetric unit. The sulfonamide functional group of this structure features S=O bond lengths ranging from 1.433 (3) to 1.439 (3) A, S—C bond lengths of 1.777 (3) and 1.773 (4) A, and S—N bond lengths of 1.622 (3) and 1.624 (3) A. When viewing the mol­ecules down the S—N bond, the isopropyl groups are gauche to the aromatic ring. On each mol­ecule, two methyl hydrogen atoms of one isopropyl group are engaged in intra­molecular C—H⋯O hydrogen bonds with a nearby sulfonamide oxygen atom. Inter­molecular C—H⋯O hydrogen bonds and C—H⋯π inter­actions link mol­ecules of the title compound in the solid state.
    • Correction
    • Source
    • Cite
    • Save
    • Machine Reading By IdeaReader
    25
    References
    0
    Citations
    NaN
    KQI
    []