Mechanical Activation on Bioleaching of Chalcopyrite: A New Insight

Mechanical activation as a means of accelerating the mineral dissolution may play an important role in chalcopyrite bioleaching. In the present work, the mechanical activation by ball-milling with 10 min, 30 min, 60 min, 90 min, 120 min and 180 min time periods of bioleaching of chalcopyrite was studied, and then evaluated by a Density Functional Theory (DFT) calculation. The results showed that the specific surface area increased sharply in the very beginning of mechanical activation and then increased slowly until the agglomeration of the particles occurred, while the chalcopyrite lattices increased with the mechanical activation. The reaction activity analyzed by cyclic voltammetry (CV) increased slowly in 30 min, increased quickly in the following 90 min, and then decreased, while the hydrophobicity analyzed by contact angles of the chalcopyrite after activation showed less of a change. The results showed that after 15 days of bioleaching, the Cu leaching by Sulfobacillus thermosulfidooxidans (S. thermosulfidooxidans) increased from 9.39% in the 0 min of mechanical activation to 87.41% in the 120 min of mechanical activation, and the copper leaching rate increased by about 78%. The DFT results provide solid proof that the activated chalcopyrite can be adsorbed more easily by cells with higher adsorption energies and stronger bonds.