Iridium-Catalyzed gamma-Selective Hydroboration of gamma-Substituted Allylic Amides.
2020
Reported here for the first time is the Ir-catalyzed gamma-selective hydroboration of gamma-substituted allylic amides under mild reaction conditions. A variety of functional groups could be compatible with reaction conditions, affording gamma-branched amides in good yields with =97% gamma-selectivity. We have also demonstrated that the obtained borylated products could be used in a series of C-O, C-F, C-Br, and C-C bond-forming reactions.
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