Copper‐Catalyzed S−C/S−N Bond Interconversions
2016
Under an atmosphere of dioxygen, copper-catalyzed de-alkylation/amination sequences provide sulfonimidamides from unprotected sulfoximines in moderate to good yields. Mechanistic studies suggest the involvement of radicals in both the C−S bond cleavage and the formation of the new N−S bond.
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