catena-Poly[[[aqua(pyridine-4-carboxylato-κN)silver(I)]-μ-hexamethylenetetraamine-κ2N:N′] dihydrate]
2011
In the title compound, {[Ag(C6H4NO2)(C6H12N4)(H2O)]·2H2O}n, the AgI atom shows a distorted triangular pyramidal geometry,, formed by two N atoms from two hexamethylenetetraamine (hmt) ligands and one N atom from a pyridine-4-carboxylate (4-pdc) ligand and one water molecule. The hmt ligands bridge the Ag atoms, forming a chain along [001]. The carboxylate group of the 4-pdc ligand is uncoordinated. O—H⋯O hydrogen bonds between the water molecules and carboxylate groups stabilize the structure.
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