Observation of Large Orientation Effect on Photoinduced Electron Transfer in Rigid Porphyrin–Quinone Compounds
1991
In order to understand the mutual orientation effect in photosynthetic electron transfer, two different kinds of quinone-linked porphyrins 1 and 2 with fixed orientation were synthesized. In the two compounds only orientation is different among various factors which control electron transfer. It has been found that the electron transfer of 1 is faster than 2 by a factor of nine.
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