First stereoselective total synthesis of helicascolides A and C

Palakodety Radha Krishna,Venkata Satyanarayana Mallula,Pendyala Venkata Arun Kumar

First stereoselective total synthesis of helicascolides A and C

2012

Palakodety Radha Krishna
Venkata Satyanarayana Mallula
Pendyala Venkata Arun Kumar

Abstract The first total synthesis of helicascolides A and C is reported via acid catalyzed acetonide deprotection followed by intramolecular lactonization in one-pot as the key step.

Keywords:

Total synthesis
Organic chemistry
Photochemistry
Acetonide
Catalysis
Intramolecular force
Stereoselectivity
Chemistry
acid catalyzed
δ lactone
Stereochemistry

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